STEREOCONTROLLED SYNTHESIS OF CYCLIC ETHERS BY INTRAMOLECULAR HETERO-MICHAEL ADDITION .3. ENANTIOMERIC SYNTHESIS OF HIGHLY FUNCTIONALIZED AND FUSED TETRAHYDROPYRANS

Citation
Jm. Palazon et al., STEREOCONTROLLED SYNTHESIS OF CYCLIC ETHERS BY INTRAMOLECULAR HETERO-MICHAEL ADDITION .3. ENANTIOMERIC SYNTHESIS OF HIGHLY FUNCTIONALIZED AND FUSED TETRAHYDROPYRANS, Tetrahedron letters, 34(34), 1993, pp. 5467-5470
Citations number
16
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
34
Issue
34
Year of publication
1993
Pages
5467 - 5470
Database
ISI
SICI code
0040-4039(1993)34:34<5467:SSOCEB>2.0.ZU;2-P
Abstract
A methodology based on intramolecular hetero-Michael addition of prope rly functionalized alkoxy-gamma-benzoyloxy-alpha,beta-unsaturated este rs for the synthesis of highly substituted and fused poly-tetrahydropy ran nuclei of marine polyether toxins with absolute control of all the stereocentres is described.