RAMAN-STUDY OF MOLECULAR-DYNAMICS OF INORGANIC FLUOROXIDIZERS IN NONAQUEOUS SOLUTIONS .1. XENON DIFLUORIDE IN ACETONITRILE

Authors
NABIEV SS OSTROUKHOVA II
Citation
Ss. Nabiev et Ii. Ostroukhova, RAMAN-STUDY OF MOLECULAR-DYNAMICS OF INORGANIC FLUOROXIDIZERS IN NONAQUEOUS SOLUTIONS .1. XENON DIFLUORIDE IN ACETONITRILE, Spectrochimica acta. Part A: Molecular spectroscopy, 49(10), 1993, pp. 1527-1535
Citations number
68
Categorie Soggetti
Spectroscopy
Journal title
Spectrochimica acta. Part A: Molecular spectroscopy → ACNP
ISSN journal
05848539
Volume
49
Issue
10
Year of publication
1993
Pages
1527 - 1535
Database
ISI
SICI code
0584-8539(1993)49:10<1527:ROMOIF>2.0.ZU;2-6
Abstract
The Raman spectra of the totally symmetric nu1(SIGMA(g)+) mode of XeF2 molecules have been measured in CH3CN solutions at various temperatur es and concentrations. The vibrational and rotational correlation func tions as well as the characteristics times have been calculated. It wa s concluded that the vibrational band width in these solutions is to b e attributed to the vibrational dephasing, whereas the contribution fr om the rotational relaxation has been found to be of less importance.