S. Ayyappan et al., OXYANION DERIVATIVES OF CUPRATE SUPERCONDUCTORS - SUPERCONDUCTING THALLIUM CUPRATE OXYSULFATE, TL0.5PB0.5SR4CU2(SO4)OY, Solid state communications, 87(6), 1993, pp. 551-552
A superconducting thallium cuprate oxysulfate of the compositlon Tl0.5
Pb0.5Sr4Cu2(SO4)O(y), (P4/mmm, a = 3.85angstrom, c = 16.6angstrom) rel
ated to the 1293 type cuprate family has been characterized. Infrared
spectra show that the sulfate ion is present as a bidentate ligand as
expected from the structure.