ELECTROCHEMICAL AND SPECTROSCOPIC PROPERTIES OF CU(II) 5-COORDINATED COMPLEXES WITH SCHIFF-BASE TYPE LIGANDS IN ORGANIC-SOLVENTS

Authors
OSSOWSKI T STROKA J
Citation
T. Ossowski et J. Stroka, ELECTROCHEMICAL AND SPECTROSCOPIC PROPERTIES OF CU(II) 5-COORDINATED COMPLEXES WITH SCHIFF-BASE TYPE LIGANDS IN ORGANIC-SOLVENTS, Polish Journal of Chemistry, 67(8), 1993, pp. 1439-1450
Citations number
25
Categorie Soggetti
Chemistry
Journal title
Polish Journal of Chemistry → ACNP
ISSN journal
01375083
Volume
67
Issue
8
Year of publication
1993
Pages
1439 - 1450
Database
ISI
SICI code
0137-5083(1993)67:8<1439:EASPOC>2.0.ZU;2-W
Abstract
Spectroscopical and electrochemical properties of Cu(II) complexes wit h a pentadentate Schiff-base have been investigated in acetonirile and DMSO solutions. The influence of the solvent and the free ligand conc entration on the reduction mechanism at the mercury electrode as well as complexation equilibria are discussed. The species present in the s olutions with free ligand excess were determined analysing the Lingane equation.