A study was performed to determine the cause of an abnormally low frac
ture toughness of an AISI 8640 resulfurized steel. The embrittlement e
ffects of phosphorus and arsenic on this steel heat-treated to a lower
bainitic structure were studied by employing fracture toughness tests
, Charpy impact tests, X-ray fluorescent spectroscopy, and scanning el
ectron microscopy (SEM). The results showed that the steel was embritt
led by phosphorus at prior austenite grain boundaries in a manner simi
lar to the tempered martensite embrittlement (TME) phenomenon. Arsenic
is also believed to be involved in the embrittlement effect, specific
ally as related to producing a reduction in the upper shelf Charpy imp
act energy. Embrittlement was manifested by a reduced fracture toughne
ss, an increase in the Charpy transition temperature, and intergranula
r fracture.