A proanthocyanidin (PA) polymer, a condensed tannin, was isolated, pur
ified and characterized from the leaves of Leptarrhena pyrolifolia. Th
e predominant extension units in the polymer were (-)-epicatechin and
(+)-gallocatechin with traces of (-)-epigallocatechin. (+)-Catechin wa
s the predominant terminal unit. The PA polymer contained both prodelp
hinidin and procyanidin units in the estimated ratio of ca 1. The cis:
trans ratio and the number-average M, of the polymer were determined
and are discussed.