PHOTO-RESPONSE OF THE [RU(BPY)3]2+ BRO3-/H+ SYSTEM IN A CONTINUOUS-FLOW STIRRED-TANK REACTOR/

Authors
SEKIGUCHI T MORI Y HANAZAKI I
Citation
T. Sekiguchi et al., PHOTO-RESPONSE OF THE [RU(BPY)3]2+ BRO3-/H+ SYSTEM IN A CONTINUOUS-FLOW STIRRED-TANK REACTOR/, Chemistry Letters, (8), 1993, pp. 1309-1312
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
8
Year of publication
1993
Pages
1309 - 1312
Database
ISI
SICI code
0366-7022(1993):8<1309:POT[BS>2.0.ZU;2-F
Abstract
Effect of photo-irradiation on the autocatalytic oxidation of [Ru(bpy) 3]Cl2 by acidic bromate has been investigated in a continuous-flow sti rred tank reactor. The photo-induced bifurcation structure and phase d iagram have been determined. It is shown that, for a certain range of the bromate concentration, the photo-irradiation can either promote or inhibit the autocatalytic oxidation of [Ru(bpy)3]2+ depending on the irradiation light power.