MIGRATION OF THE HYDROXYL GROUP OF N-HYDROXY-N-PHENYLAMIDES TO THE PHENYL GROUP WITH TERTIARY PHOSPHINES AND TETRACHLOROMETHANE - A NOVEL TRANSHYDROXYLATION REACTION

Authors
KIKUGAWA Y MITSUI K
Citation
Y. Kikugawa et K. Mitsui, MIGRATION OF THE HYDROXYL GROUP OF N-HYDROXY-N-PHENYLAMIDES TO THE PHENYL GROUP WITH TERTIARY PHOSPHINES AND TETRACHLOROMETHANE - A NOVEL TRANSHYDROXYLATION REACTION, Chemistry Letters, (8), 1993, pp. 1369-1372
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
8
Year of publication
1993
Pages
1369 - 1372
Database
ISI
SICI code
0366-7022(1993):8<1369:MOTHGO>2.0.ZU;2-U
Abstract
The hydroxyl group of N-hydroxy-N-phenylamides rearranges mainly to th e ortho position of the N-phenyl ring by the system (n-Bu)3P-CCl4-CH3C N; use of less than a stoichiometric amount of (n-Bu)3P is effective f or this reaction.