MONONUCLEAR ARYLAMIDO COMPLEXES OF IRIDIUM(I)

Authors
RAHIM M WHITE C RHEINGOLD AL AHMED KJ
Citation
M. Rahim et al., MONONUCLEAR ARYLAMIDO COMPLEXES OF IRIDIUM(I), Organometallics, 12(7), 1993, pp. 2401-2403
Citations number
39
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
12
Issue
7
Year of publication
1993
Pages
2401 - 2403
Database
ISI
SICI code
0276-7333(1993)12:7<2401:MACOI>2.0.ZU;2-R
Abstract
The preparation and the first structural characterization of arylamido complexes of Ir(I), having the general formula trans-Ir(CO)(NHAr)(PPh 3)2, where Ar = Ph (1), p-C6H4Me (2), 2,6-C6H3Me2 (3), are described. Preliminary results of their facile insertion reactions with CO and CO 2 are also discussed.