SYNTHESIS OF A NICKEL(0) COMPLEX OF A METHOXY-SUBSTITUTED TRIBENZOCYCLOTRIYNE - X-RAY CRYSTALLOGRAPHIC EVIDENCE FOR AN INTERMOLECULAR C-H-NI AGOSTIC INTERACTION

Authors
YOUNGS WJ KINDER JD BRADSHAW JD TESSIER CA
Citation
Wj. Youngs et al., SYNTHESIS OF A NICKEL(0) COMPLEX OF A METHOXY-SUBSTITUTED TRIBENZOCYCLOTRIYNE - X-RAY CRYSTALLOGRAPHIC EVIDENCE FOR AN INTERMOLECULAR C-H-NI AGOSTIC INTERACTION, Organometallics, 12(7), 1993, pp. 2406-2407
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
12
Issue
7
Year of publication
1993
Pages
2406 - 2407
Database
ISI
SICI code
0276-7333(1993)12:7<2406:SOANCO>2.0.ZU;2-R
Abstract
The synthesis and characterization of a nickel-(0) complex of 5,6,11,1 2,17,18-hexadehydro-1,4,7,10,13, 16-hexamethoxytribenzo[a,e,i]cyclodod ecene (2) is described. The crystal structure revealed the presence of intermolecular agostic C-H---Ni and intermolecular C-H---O interactio ns.