SYMMETRICALLY BRIDGED DIMERIC VANADIUM NITRIDO COMPOUNDS - SYNTHESIS AND CHARACTERIZATION OF [(ETA-C5ME5)V(N)CL]2

Authors
HADDAD TS AISTARS A ZILLER JW DOHERTY NM
Citation
Ts. Haddad et al., SYMMETRICALLY BRIDGED DIMERIC VANADIUM NITRIDO COMPOUNDS - SYNTHESIS AND CHARACTERIZATION OF [(ETA-C5ME5)V(N)CL]2, Organometallics, 12(7), 1993, pp. 2420-2422
Citations number
40
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
12
Issue
7
Year of publication
1993
Pages
2420 - 2422
Database
ISI
SICI code
0276-7333(1993)12:7<2420:SBDVNC>2.0.ZU;2-R
Abstract
Reaction of trimethylsilyl azide with [(eta-C5Me5)VCl2]3 produces a di meric vanadium nitrido compound, [(eta-C5Me5)V(N)Cl]2. Spectroscopic, structural, and reactivity data indicate that this compound possesses stable and symmetric V(N)V interactions in the first example of a M2N2 compound.