DIMERIZATION DOUBLE SILYLATION OF 1,3-DIENES USING ORGANODISILANES CATALYZED BY A PALLADIUM COMPLEX

Authors
OBORA Y TSUJI Y KAWAMURA T
Citation
Y. Obora et al., DIMERIZATION DOUBLE SILYLATION OF 1,3-DIENES USING ORGANODISILANES CATALYZED BY A PALLADIUM COMPLEX, Organometallics, 12(7), 1993, pp. 2853-2856
Citations number
47
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
12
Issue
7
Year of publication
1993
Pages
2853 - 2856
Database
ISI
SICI code
0276-7333(1993)12:7<2853:DDSO1U>2.0.ZU;2-V
Abstract
Disilanes (1a-e) react with 1,3-dienes (2a-d) in the presence of a pal ladium catalyst to give dimerization-double silylation products (3a-k) regio- and stereoselectively in high yields. Pd(DBA)2 shows high cata lytic activity in DMF or dioxane as the solvent at room temperature. N o crossover silylations occur.