Zm. Saleh et al., TRAPPING AND RECOMBINATION OF PHOTOGENERATED CARRIERS IN AS-GROWN HIGH-TEMPERATURE-ANNEALED AND LIGHT-SOAKED A-SIH, JPN J A P 1, 32(8), 1993, pp. 3376-3384
Our previous results of light-induced electron spin resonance (LESR) i
ndicate that, in hydrogenated amorphous silicon (a-Si:H), light-induce
d defects differ from those formed during deposition or high-temperatu
re annealing. The concept of demarcation was used to interpret these d
ifferences in terms of higher energy levels for light-induced defects.
In this study, the constant photocurrent method (CPM), dark conductiv
ity and transient-LESR are used to supply new evidence for the differe
nces and to conduct two tests on our hypothesis. The demarcation energ
ies for electrons and holes are shifted by varying the temperature or
bias-light intensity for transient-LESR. In striking agreement with ou
r hypothesis, we find that the light-induced changes in the LESR line
shape (an increase in the broad component relative to the narrow one u
pon light exposure) become indeed more dramatic as the demarcation ene
rgies move closer to the midgap.