Carbohydrate derivatives with surfactant properties are known for a lo
ng time. Nevertheless, their large scale commercial production has not
been realized in the past, especially due to the lack of suitable eco
nomical manufacturing procedures. Among the well-known carbohydrate su
rfactant structures, the long chain alkyl polyglucosides are expected
to succeed within the group of large scale leading surfactants. The de
velopment of the chemistry of carbohydrate surfactants is reviewed, pa
rticulary describing manfacturing process options for alkyl polyglucos
ides. Present large scale glucoside surfactant manufacture is based on
a number of decisive product and process improvements, leading to pro
ducts which meet the demands of the surfactant market regarding perfor
mance, quality and price. Alkyl polyglucosides are a new category of m
ild, moderately foaming, highly soluble nonionic surfactants suitable
for many applications and industries. Their unique performance and for
mulating properties are summarized.