APPLICATION OF ACOUSTOPHORESIS IN A STUDY ON SOLUTE SUPPORT INTERACTIONS FOR THE PREPARATION OF SUPPORTED COBALT MOLYBDENUM CATALYSTS

Citation
M. Deboer et al., APPLICATION OF ACOUSTOPHORESIS IN A STUDY ON SOLUTE SUPPORT INTERACTIONS FOR THE PREPARATION OF SUPPORTED COBALT MOLYBDENUM CATALYSTS, Applied catalysis. A, General, 102(1), 1993, pp. 35-51
Citations number
46
Categorie Soggetti
Chemistry Physical","Environmental Sciences
ISSN journal
0926860X
Volume
102
Issue
1
Year of publication
1993
Pages
35 - 51
Database
ISI
SICI code
0926-860X(1993)102:1<35:AOAIAS>2.0.ZU;2-9
Abstract
Acoustophoresis has been used to investigate the interaction between s uspended mineral oxides (SiO2 and Al2O3) and aqueous solutions of coba lt (II) chloride, molybdenum (III) chloride and ammonium heptamolybdat e (AHM) as a function of the pH. The measured electrokinetic sonic amp litude (ESA) is directly related to the zeta-potential and gives infor mation on the iso-electric point of the mineral oxides, that are used as supports for catalysts. The interaction between the solutes and the suspended mineral oxides is an important parameter for the preparatio n of supported catalysts, which can be studied perfectly by means of a coustophoresis. The specific adsorption of cobalt and molybdenum on si lica and alumina has been considered.