DILUENT EFFECT ON THE EXTRACTION PROPERTIES OF BIFUNCTIONAL NEUTRAL ORGANOPHOSPHORUS COMPOUNDS (BNOPC) .1. ETHERS CONTAINING FLUORINE AS DILUENTS FOR BNOPC

Authors
SHADRIN AY BABAIN VA SMIRNOV IV KISELEVA RN CHMUTOVA MK PRIBYLOVA GA MYASOEDOV BF
Citation
Ay. Shadrin et al., DILUENT EFFECT ON THE EXTRACTION PROPERTIES OF BIFUNCTIONAL NEUTRAL ORGANOPHOSPHORUS COMPOUNDS (BNOPC) .1. ETHERS CONTAINING FLUORINE AS DILUENTS FOR BNOPC, Radiochemistry, 35(2), 1993, pp. 191-194
Citations number
7
Categorie Soggetti
Chemistry Analytical","Chemistry Inorganic & Nuclear
Journal title
Radiochemistry → ACNP
ISSN journal
10663622
Volume
35
Issue
2
Year of publication
1993
Pages
191 - 194
Database
ISI
SICI code
1066-3622(1993)35:2<191:DEOTEP>2.0.ZU;2-4
Abstract
A new class of diluents for BNOPC, ethers containing fluorine (ECF), i s investigated. Solutions of BNOPC in ECF are shown highly to extract rare earths and transplutonium elements. They can be used to separate macroscopic amounts of these elements without a solubilizer. It is dis covered that the diluent properties significantly more strongly affect the extraction ability of BNOPC containing aryl substituents on the P than that of those with alkyl substituents.