VOLTAMMETRIC WAVESHAPES MEASURED IN FLOWING SYSTEMS - MASS TRANSPORT-LIMITED TAFEL ANALYSIS OF SOME NONSIMPLE SYSTEMS

Authors
COMPTON RG FISHER AC SANDERS GHW
Citation
Rg. Compton et al., VOLTAMMETRIC WAVESHAPES MEASURED IN FLOWING SYSTEMS - MASS TRANSPORT-LIMITED TAFEL ANALYSIS OF SOME NONSIMPLE SYSTEMS, Electroanalysis, 5(7), 1993, pp. 615-617
Citations number
12
Categorie Soggetti
Chemistry Analytical
Journal title
Electroanalysis → ACNP
ISSN journal
10400397
Volume
5
Issue
7
Year of publication
1993
Pages
615 - 617
Database
ISI
SICI code
1040-0397(1993)5:7<615:VWMIFS>2.0.ZU;2-D
Abstract
Analytical theory is presented which allows rigorous mass transport-co rrected Tafel analysis for the reversible electrode processes (1) 2B r eversible A2 + 2e- and (2) B2 reversible 2A + 2e- occurring at electro des in flowing systems. Predictions are compared with the conclusions of numerical finite-difference modelling for both wall-jet and channel flow cell geometries. Excellent agreement is found.