''Hot particles'' collected in 1987-1988 within 30-km zone around Cher
nobyl NPP were different in radionuclide composition and Pu fractionat
ion coefficients, Ru-106 and Cs-137 as compared to Ce-144. Pu was foun
d in ''hot particles'' in different forms. The particles with composit
ion close to nuclear fuel exhibit the minimum Pu solubility. A positiv
e correlation between unsoluble Pu and Ce-144 was found in the particl
es. Maximum Pu solubility was found in the particles enriched in Ce-14
4 (only 17-32% of unsoluble Pu). A conclusion has been made that high
amounts of soluble forms of Pu in ''hot particles'' (up to 30-40%) can
leave these particles to involve in biological cycles. A possible com
position of ''hot particles'' formed as a result of solid state conden
sation of gas-vapor cloud and mechanisms of insertion of radionuclides
into these particles were