THE SEPARATION OF TELLURIUM AND SELENIUM BY POLYURETHANE FOAM SORBENTS

Authors
Citation
Ii. Stewart et A. Chow, THE SEPARATION OF TELLURIUM AND SELENIUM BY POLYURETHANE FOAM SORBENTS, Talanta, 40(9), 1993, pp. 1345-1352
Citations number
11
Journal title
Talanta
ISSN journal
00399140 → ACNP
Volume
40
Issue
9
Year of publication
1993
Pages
1345 - 1352
Database
ISI
SICI code
0039-9140(1993)40:9<1345:TSOTAS>2.0.ZU;2-M
Abstract
Tellurium and selenium can be sorbed from hydrochloric acid and hydrob romic acid solution by both polyether and polyester-based polyurethane foam. Although some acid is needed, the substitution of sodium chlori de or sodium bromide increases the extraction significantly. Tellurium is extracted rapidly with > 99% sorbed in 2 min from 1.0/5.0M and 2.0 /4.0M hydrochloric acid/sodium bromide. Selenium can also be sorbed qu antitatively but much more slowly so that a separation is possible bas ed on the relative rates of extraction. The capacity of polyether foam is 3% by weight of tellurium.