SELECTIVE OXIDATION OF OPTICALLY-ACTIVE SEC,SEC-1,2-DIOLS BY DIOXIRANES - A PRACTICAL METHOD FOR THE SYNTHESIS OF HOMOCHIRAL ALPHA-HYDROXY KETONES IN HIGH OPTICAL PURITY

Authors
DACCOLTI L DETOMASO A FUSCO C ROSA A CURCI R
Citation
L. Daccolti et al., SELECTIVE OXIDATION OF OPTICALLY-ACTIVE SEC,SEC-1,2-DIOLS BY DIOXIRANES - A PRACTICAL METHOD FOR THE SYNTHESIS OF HOMOCHIRAL ALPHA-HYDROXY KETONES IN HIGH OPTICAL PURITY, Journal of organic chemistry, 58(14), 1993, pp. 3600-3601
Citations number
48
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of organic chemistry → ACNP
ISSN journal
00223263
Volume
58
Issue
14
Year of publication
1993
Pages
3600 - 3601
Database
ISI
SICI code
0022-3263(1993)58:14<3600:SOOOSB>2.0.ZU;2-2
Abstract
By employing either dimethyldioxirane or its trifluoromethyl analog, t he direct, high-yield conversion of one cyclic and three open chain op tically sec,sec-1,2-diols to the corresponding alpha-hydroxy ketones i n high optical yield has been achieved.