ADDITION OF QUADRICYCLANE TO C-60 - EASY ACCESS TO FULLERENE DERIVATIVES BEARING A REACTIVE DOUBLE-BOND IN THE SIDE-CHAIN

Authors
PRATO M MAGGINI M SCORRANO G LUCCHINI V
Citation
M. Prato et al., ADDITION OF QUADRICYCLANE TO C-60 - EASY ACCESS TO FULLERENE DERIVATIVES BEARING A REACTIVE DOUBLE-BOND IN THE SIDE-CHAIN, Journal of organic chemistry, 58(14), 1993, pp. 3613-3615
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of organic chemistry → ACNP
ISSN journal
00223263
Volume
58
Issue
14
Year of publication
1993
Pages
3613 - 3615
Database
ISI
SICI code
0022-3263(1993)58:14<3613:AOQTC->2.0.ZU;2-C
Abstract
The reaction of C60 with quadricyclane gives a stable 6,6 adduct which has been spectroscopically characterized. The double bond of the [2.2 .1]bicycloheptene moiety reacts readily with electrophiles (e.g., PhSC l).