ASYMMETRIC SELENOMETHOXYLATION OF OLEFINS INVOLVING A CHIRAL C2 SYMMETRICAL ELECTROPHILIC ORGANOSELENIUM REAGENT

Authors
DEZIEL R GOULET S GRENIER L BORDELEAU J BERNIER J
Citation
R. Deziel et al., ASYMMETRIC SELENOMETHOXYLATION OF OLEFINS INVOLVING A CHIRAL C2 SYMMETRICAL ELECTROPHILIC ORGANOSELENIUM REAGENT, Journal of organic chemistry, 58(14), 1993, pp. 3619-3621
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of organic chemistry → ACNP
ISSN journal
00223263
Volume
58
Issue
14
Year of publication
1993
Pages
3619 - 3621
Database
ISI
SICI code
0022-3263(1993)58:14<3619:ASOOIA>2.0.ZU;2-9
Abstract
A new chiral C2 symmetrical organoselenium reagent has been synthesize d; this compound, in the presence of methanol, reacts with high facial selectivity with olefins to afford the anti selenomethoxylated adduct s in very good yields.