P. Sevcik et L. Kolinkova, EFFECT OF PRESSURE DECREASE ON THE BELOUSOV-ZHABOTINSKII OSCILLATION REACTION, Collection of Czechoslovak Chemical Communications, 58(6), 1993, pp. 1309-1314
The decrease of pressure from 101.3 kPa to 5.25 kPa has an effect on t
he parameters of the Belousov-Zhabotinskii reaction in batch system in
the atmosphere of N2, O2, and CO2. Under the anaerobic conditions. th
e difference in the form of the reduced phase of oscillatory cycle per
sists even at vigorous stirring. The role of nucleation. supersaturati
on, atmosphere. and rate of stirring in these effects is discussed.