REDUCTIVE ELECTROPHILIC SUBSTITUTION OF PYROGALLOL DERIVATIVES - SYNTHESIS OF 2,3-DISUBSTITUTED PHENOLS

Citation
U. Azzena et al., REDUCTIVE ELECTROPHILIC SUBSTITUTION OF PYROGALLOL DERIVATIVES - SYNTHESIS OF 2,3-DISUBSTITUTED PHENOLS, Tetrahedron letters, 34(35), 1993, pp. 5635-5638
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
34
Issue
35
Year of publication
1993
Pages
5635 - 5638
Database
ISI
SICI code
0040-4039(1993)34:35<5635:RESOPD>2.0.ZU;2-H
Abstract
1,2-Dimethoxy-3-methoxymethoxybenzene, 1, was used as the starting mat erial for the transformation of a 1,2,3-trioxybenzene into various 1-o xy-2,3-dicarbobenzenes, via regioselective reductive electrophilic sub stitution of the 2-methoxy group followed by Pd-catalyzed cross-coupli ng reaction.