REVISED STRUCTURES FOR TU 1718B AND VALCLAVAM

Citation
Je. Baldwin et al., REVISED STRUCTURES FOR TU 1718B AND VALCLAVAM, Tetrahedron letters, 34(35), 1993, pp. 5645-5648
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
34
Issue
35
Year of publication
1993
Pages
5645 - 5648
Database
ISI
SICI code
0040-4039(1993)34:35<5645:RSFT1A>2.0.ZU;2-3
Abstract
The structures of Tu 1718B and valclavam, antibiotics produced by Stre ptomyces antibioticus ssp. antibioticus Tu 1718, have been reassigned as valyl-beta-delta-dihydroxylysine (4) and the clavam (5) respectivel y, on the basis of NMR experiments and the observation that the former is a degradation product of the latter.