A mathematical model of biomass gasification in a fluidized bed has be
en developed. It considers axial variations of concentrations and temp
erature in the bubble and emulsion phases. The mass balance involves i
nstantaneous oxidation and equilibrium devolatilization of the biomass
, kinetics of solid-gas gasification reactions as well as of gaseous p
hase reactions and interphase mass transfer and gas convection. The en
ergy balance is solved locally for each vertical volume element, and g
lobally on the reactor by iteration on the temperature at the bottom o
f the bed. Three parameters have been adjusted based on the experiment
al results: the heat transfer coefficient at the wall, the weighting o
f the kinetics of the water-gas shift reaction and the fraction of bio
mass carbon remaining as char after devolatilization. The model is use
d to simulate a pilot scale (50 kg/h) biomass gasifier, and its predic
tions compared to experimental measurements. The temperature and gaseo
us concentrations are estimated with good accuracy for the experiments
using a wood feedstock, except for the concentration of hydrogen whic
h is overestimated.