L. Lorenzen et Jsj. Vandeventer, THE IDENTIFICATION OF REFRACTORINESS IN GOLD ORES BY THE SELECTIVE DESTRUCTION OF MINERALS, Minerals engineering, 6(8-10), 1993, pp. 1013-1023
With the increasingly lower grades of ore mined, the introduction of b
ackfill mining, and the reduction of profit margins, it has become imp
erative to increase the efficiency of gold dissolution. Diagnostic lea
ching (selective decomposition of refractory minerals associated with
gold) tests conducted on a large number of composite residue samples,
indicated that a large portion of the gold in the residue was leachabl
e (up to 60%). About half of this leachable gold was dissolved by a qu
ick cyanide wash, indicating that it was precipitated gold. A signific
ant portion of the non-leachable gold in the residue was coated with v
arious films, of which iron oxide was the major one. These films varie
d in nature from oxides, sulphates, carbonates and cyanide complexes.
The complexes can be destroyed, depending on the nature of the film by
interstage dilute acid and/or cyanide washes in an agitated vessel. T
he major cyanide consumers in the residue streams were found to be cop
per, nickel and soluble sulphides.The reality of an ultimate residue (
thus only gold enclosed in fine quartz remains), is within the reach o
f most of the major gold producing mines, as at least 50% of the gold
in the residue could be recovered at little additional cost. It is sug
gested that residue values at many gold plants are unsatisfactorily hi
gh due to the complex nature of the ore and because plant personnel do
not utilize all available knowledge on gold dissolution.