ASYMMETRIC-SYNTHESIS OF A STERICALLY RIGID - BINAPHTHYL-BRIDGED CHIRAL METALLOCENE - ASYMMETRIC CATALYTIC EXPOXIDATION OF UNFUNCTIONALIZED ALKENES

Authors
HALTERMAN RL RAMSEY TM
Citation
Rl. Halterman et Tm. Ramsey, ASYMMETRIC-SYNTHESIS OF A STERICALLY RIGID - BINAPHTHYL-BRIDGED CHIRAL METALLOCENE - ASYMMETRIC CATALYTIC EXPOXIDATION OF UNFUNCTIONALIZED ALKENES, Organometallics, 12(8), 1993, pp. 2879-2880
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
12
Issue
8
Year of publication
1993
Pages
2879 - 2880
Database
ISI
SICI code
0276-7333(1993)12:8<2879:AOASR->2.0.ZU;2-M
Abstract
The synthesis of the first enantiomerically enriched C2-symmetrical br idged titanocene dichloride which incorporates homotopic cyclopentadie nyl moieties is described, along with its application as an asymmetric epoxidation catalyst.