Ck. Pan et Fl. King, ION FORMATION PROCESSES IN THE AFTERPEAK TIME REGIME OF PULSED GLOW-DISCHARGE PLASMAS, Journal of the American Society for Mass Spectrometry, 4(9), 1993, pp. 727-732
The formation of ions following the termination of power in a pulsed g
low discharge ion source is investigated. The populations of ionized s
pecies containing sputtered atoms M+, M2+, and MAr+ are observed to ma
ximize after the termination of discharge power. Collisions involving
sputtered atoms and metastable argon atoms, Penning and associative io
nization, are considered to be responsible for the formation of ions i
n the discharge afterpeak time regime. The domination of these ion for
mation processes during the afterpeak time regime is supported by the
results from investigations of discharge operating parameters, metasta
ble argon atom quenching, and ion kinetic energy distributions.