ORIENTATIONAL ORDER IN POLYETHYLENE FOILS - A POLARIZED RAMAN-SPECTROSCOPIC STUDY

Polarized Raman spectroscopy was used to determine the order parameter s of the orientational distribution function for a series of stretched polyethylene foils with a relatively low degree of molecular orientat ional order. By combining measurements of the foil under study and of an isotropic polyethylene foil, simple backscattering experiments are sufficient to determine the orientation order parameters of the foil w ith molecular orientation. Practical considerations for obtaining pola rized Raman spectra are discussed. The results are in good agreement w ith the order parameters obtained by IR dichroism and wide-angle x-ray diffraction. Differences between the various methods are discussed. T he Raman method proves to be a relatively rapid method for obtaining i nformation concerning the molecular orientation in polyethylene films.