PARTIAL MOLAR VOLUMES OF SEVERELY HINDERED BETA-DIKETONES WITH ALPHA-ADAMANTYL GROUPS

Citation
Mf. Reystolle et al., PARTIAL MOLAR VOLUMES OF SEVERELY HINDERED BETA-DIKETONES WITH ALPHA-ADAMANTYL GROUPS, Journal of chemical and engineering data, 38(3), 1993, pp. 356-357
Citations number
7
Categorie Soggetti
Engineering, Chemical",Chemistry
ISSN journal
00219568
Volume
38
Issue
3
Year of publication
1993
Pages
356 - 357
Database
ISI
SICI code
0021-9568(1993)38:3<356:PMVOSH>2.0.ZU;2-9
Abstract
Partial molar volumes of several alpha-adamantyl beta-diketones and ad amantane were determined by density measurements. The effect of solven t and structure of the alpha-substituents and the size of the end grou ps were analyzed. Good agreement was observed between the experimental molar volumes and the values calculated by group contributions; in al l the cases the differences were less than 4%.