REACTIONS OF 2-AMINO-1-AZAAZULENES WITH DIPHENYLCYCLOPROPENONE

Authors
ABE N KAKEHI A
Citation
N. Abe et A. Kakehi, REACTIONS OF 2-AMINO-1-AZAAZULENES WITH DIPHENYLCYCLOPROPENONE, Heterocycles, 36(9), 1993, pp. 1961-1964
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Heterocycles → ACNP
ISSN journal
03855414
Volume
36
Issue
9
Year of publication
1993
Pages
1961 - 1964
Database
ISI
SICI code
0385-5414(1993)36:9<1961:RO2WD>2.0.ZU;2-C
Abstract
Reaction of 2-amino-1-azaazulene with diphenylcyclopropenone gave 2,3, 10b-tetrahydro-4,10b-diazabenz[a]azulen-3-one, which rearranged to N-( 1-azaazulen-2-yl)-alpha-cis-stylbenecarboxamide and (1-azaazulen-2-yl) -alpha-trans-stylbenecarboxamide by heating. Some structures of these products were determined by the X-ray structure analyses. The reaction mechanism is discussed.