MASS-SPECTROMETRIC AND IR SPECTROSCOPIC CHARACTERIZATION OF MONOMERICMOLECULAR RUTHENIUM OXIDE TETRAFLUORIDE

Authors
BRISDON AK HOPE EG HOLLOWAY JH LEVASON W OGDEN JS
Citation
Ak. Brisdon et al., MASS-SPECTROMETRIC AND IR SPECTROSCOPIC CHARACTERIZATION OF MONOMERICMOLECULAR RUTHENIUM OXIDE TETRAFLUORIDE, Journal of fluorine chemistry, 64(1-2), 1993, pp. 117-123
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
64
Issue
1-2
Year of publication
1993
Pages
117 - 123
Database
ISI
SICI code
0022-1139(1993)64:1-2<117:MAISCO>2.0.ZU;2-E
Abstract
Monomeric molecular ruthenium oxide tetrafluoride, prepared by the rea ction of RuF5 with glass at c. 300-degrees-C, has been characterised b y mass spectrometry and matrix-isolation IR spectroscopy. RuOF4 exhibi ts C4v symmetry, in common with all the known transition-metal oxide f luorides, with the O-Ru-F angle calculated to be equal to 110 +/- 6-de grees.