FUNCTIONALIZATION OF POLYDIPHENYLCARBOSIL ANE

Authors
UHLIG W
Citation
W. Uhlig, FUNCTIONALIZATION OF POLYDIPHENYLCARBOSIL ANE, Journal of organometallic chemistry, 456(1), 1993, pp. 30000001-30000003
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
456
Issue
1
Year of publication
1993
Pages
30000001 - 30000003
Database
ISI
SICI code
0022-328X(1993)456:1<30000001:FOPA>2.0.ZU;2-8
Abstract
Polydiphenylcarbosilane, obtained by a simple polycondensation of the monomers dichlorodiphenylsilane and dibromomethane with sodium as redu cing agent, reacts with triflic acid to triflate-substituted polycarbo silanes. The conversion of these polymers with compounds containing ac idic element hydrogen bonds leads to numerous new functional substitut ed polycarbosilanes.