EASY ACCESS TO CYCLOPENTANOID STRUCTURES .1. PREPARATION AND TRANSPOSITION OF TRICYCLO[M.N.0.0(2,M-2,3,M+2-TRIOL DERIVATIVES(1)]ALCA)

Authors
JAMARTGREGOIRE B BROSSE N IANELLI S NARDELLI M CAUBERE P
Citation
B. Jamartgregoire et al., EASY ACCESS TO CYCLOPENTANOID STRUCTURES .1. PREPARATION AND TRANSPOSITION OF TRICYCLO[M.N.0.0(2,M-2,3,M+2-TRIOL DERIVATIVES(1)]ALCA), Journal of organic chemistry, 58(17), 1993, pp. 4572-4578
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of organic chemistry → ACNP
ISSN journal
00223263
Volume
58
Issue
17
Year of publication
1993
Pages
4572 - 4578
Database
ISI
SICI code
0022-3263(1993)58:17<4572:EATCS.>2.0.ZU;2-H
Abstract
Methylenecyclobutanols 1, conveniently obtained by 1,2-cycladiene cond ensation of ketone enolates, were used as starting materials for the e asy preparation of polycyclic cyclopentane derivatives. Thus, the tran sposition and transposition-elimination of triol derivatives 3, 5, and 6 led to the synthesis of a series of polycyclic cyclopentan- or cycl opentenones. The stereochemistries of the transpositions were studied and mechanisms were proposed.