EXCITONIC INTERACTIONS IN THE LIGHT-HARVESTING ANTENNA OF PHOTOSYNTHETIC PURPLE BACTERIA AND THEIR INFLUENCE ON PICOSECOND ABSORBENCY DIFFERENCE SPECTRA
Vi. Novoderezhkin et Ap. Razjivin, EXCITONIC INTERACTIONS IN THE LIGHT-HARVESTING ANTENNA OF PHOTOSYNTHETIC PURPLE BACTERIA AND THEIR INFLUENCE ON PICOSECOND ABSORBENCY DIFFERENCE SPECTRA, FEBS letters, 330(1), 1993, pp. 5-7
A new model of the light-harvesting antenna (core complex) of purple p
hotosynthetic bacteria is proposed based on excitonic interactions in
circular aggregates of bacteriochlorophyll molecules. The calculated a
bsorbance difference spectra of circular aggregates demonstrate all sp
ecial features observed in the experimental spectra of purple bacteria
. In particular, the absorption changes with high amplitude of bleachi
ng at the long-wavelength side of the absorption band at different exc
itation energy are predicted.