SELECTIVE FORMATION OF NA-X ZEOLITE FROM COAL FLY-ASH BY FUSION WITH SODIUM-HYDROXIDE PRIOR TO HYDROTHERMAL REACTION

Hydrothermal treatment of fly ash with alkali gives various types of z eolites such as Na-Pl, Na-A and hydroxysodalite, where the zeolite zon e was formed like an egg white, covering the central core of fly ash p articles, as evinced in the previous paper. By fusion with sodium hydr oxide, most of the fly ash particles were converted into sodium salts such as silicate and aluminate, from which hydrothermal reaction witho ut stirring favourably resulted in the formation of Na-X zeolite. Crys tallinity of Na-X zeolite as high as 62% was attained at the optimum c ondition of NaOH/fly ash = 1.2 and a fusion temperature of 823 K. Fly ash contains 14 wt% mullite (3Al2O3.2SiO2), which was revealed to be a less-active crystalline component for zeolite formation. Aluminium-en riched fly ash gave Na-A in place of Na-X zeolite. Scanning electron m icroscope images of cubic and octahedral crystals characteristic of Na -A and Na-X zeolite, respectively, obtained from fly ash, are given.