Tannins are a possible replacement for red lead in primary paints used
for the corrosion protection of steel structures but their reaction m
echanism is controversial. Using gallic acid as a model compound the r
eaction of tannins with rust is being investigated using FTIR spectros
copy, X-ray diffraction and electrochemical reduction. The results obt
ained by the different methods suggest that gallic acid inhibits the t
ransformation of lepidocrocite into magnetite.