THE DSD MODEL IN HEPTACOORDINATE STEREOCHEMISTRY - A COMPARISON WITH EXPERIMENT

Authors
Citation
J. Brocas, THE DSD MODEL IN HEPTACOORDINATE STEREOCHEMISTRY - A COMPARISON WITH EXPERIMENT, Journal of mathematical chemistry, 14(2), 1993, pp. 153-174
Citations number
41
Categorie Soggetti
Chemistry,Mathematics
ISSN journal
02599791
Volume
14
Issue
2
Year of publication
1993
Pages
153 - 174
Database
ISI
SICI code
0259-9791(1993)14:2<153:TDMIHS>2.0.ZU;2-G
Abstract
The diamond-square-diamond or dsd model provides a simple description for heptacoordinate interconversion. We compare it to NMR information. It appears that the model is almost always compatible with experiment al facts, at least when the dsd processes do not lead to isomerization .