Prj. Gaffney et Cb. Reese, PREPARATION OF 2-O-ARACHIDONOYL-1-O-STEAROYL-SN-GLYCEROL AND OTHER DI-O-ACYL GLYCEROL DERIVATIVES, Tetrahedron letters, 38(14), 1997, pp. 2539-2542
R(-)-2,3- and S(+)-1,2-O-Isopropylidene-sn-glycerols (4 and 9) are con
verted into 2-O-arachidonoyl-1-O-stearoyl and 2-O-arachidonoyl-3-O-ste
aroyl-sn-glycerols (2 and 3, respectively); glycerol is also converted
into its racemic 1,2- and its symmetrical 1,3-di-O-linoleoyl derivati
ves (14 and 17, respectively). (C) 1997 Elsevier Science Ltd.