CALCULATED LONDON PI-ELECTRON MAGNETIC-PROPERTIES OF SOME CARBON-ATOMFRAGMENTS EXTANT ON THE SURFACE OF ICOSAHEDRAL C-60 (BUCKMINSTERFULLERENE)

Citation
Brm. Decastro et al., CALCULATED LONDON PI-ELECTRON MAGNETIC-PROPERTIES OF SOME CARBON-ATOMFRAGMENTS EXTANT ON THE SURFACE OF ICOSAHEDRAL C-60 (BUCKMINSTERFULLERENE), Croatica chemica acta, 66(1), 1993, pp. 49-58
Citations number
57
Categorie Soggetti
Chemistry
Journal title
ISSN journal
00111643
Volume
66
Issue
1
Year of publication
1993
Pages
49 - 58
Database
ISI
SICI code
0011-1643(1993)66:1<49:CLPMOS>2.0.ZU;2-X
Abstract
Semi-empirical calculations, of varying degrees of sophistication, are effected in order to predict the >>London<< pi-electron magnetic-prop erties of several carbon-atom fragments - some large, some small - tha t are extant on the spherical surface of the truncated-icosahedral C60 cluster known as Buckminsterfullerene. Calculations by the least-appr oximate of the methods that have been applied predict every one of the Buckminsterfullerene fragments studied to display >>London<< pi-elect ron magnetic-properties that are, overall, diamagnetic - to the extent of between ca. 1/3 of, and ca. 5 times, the benzene value.