A thin-film transistor (TFT) with high carrier mobility has been fabri
cated using precursor-route poly(2,5-thienylenevinylene) (PTV) as semi
conductor. The carrier mobility has been determined to be 0.22 cm2/V s
, which is in the same level of that of amorphous silicon TFT. It has
also been made clear that the carrier mobility is linearly proportiona
l to the conversion ratio from the insulated precursor polymer to pi-c
onjugated PTV. The pi-conjugation length is crucial to obtain high car
rier mobility in pi-conjugated polymer TFT.