M. Nishitsuji et A. Tamura, RAPID THERMAL ANNEALING OF SI-IMPLANTED GAAS USING THE GA-DOPED SPIN-ON GLASS-FILMS, Applied physics letters, 63(10), 1993, pp. 1384-1386
We have studied rapid thermal annealing (RTA) of Si-implanted GaAs usi
ng Ga-doped spin-on glass (SOG) film for the first time. Three kinds o
f films such as Ga-doped SOG, undoped SOG, and SiO2 formed by the chem
ical vapor deposition (CVD) method were compared. The annealed GaAs la
yers were characterized by sheet resistance, capacitance-voltage (C-V)
, deep level transient spectroscopy (DLTS), and photoluminescence (PL)
measurements. The secondary ion mass spectroscopy (SIMS) measurement
was also performed to investigate the atomic behavior at the insulatin
g film/GaAs interface during annealing. Ga-doped SOG film as an anneal
cap of GaAs offers activation efficiency as compared with CVD-SiO2 an
d undoped SOG film. The PL spectra for the annealed sample with Ga-dop
ed SOG cap exhibited the lowest intensity at 1.36 eV broad band emissi
on, which suggests the suppression of the generation of Ga-vacancy rel
ated acceptor level during annealing.