ESTIMATES OF ELECTRON RANGE AND ION MOBILITY IN CHOLESTERYL OLEYL CARBONATE

Authors
Citation
Pk. Watson, ESTIMATES OF ELECTRON RANGE AND ION MOBILITY IN CHOLESTERYL OLEYL CARBONATE, Journal of molecular liquids, 56, 1993, pp. 359-377
Citations number
13
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
ISSN journal
01677322
Volume
56
Year of publication
1993
Pages
359 - 377
Database
ISI
SICI code
0167-7322(1993)56:<359:EOERAI>2.0.ZU;2-B
Abstract
An electron beam has been used as an ohmic contact to films of cholest eryl oleyl carbonate (COC). Incremental charging experiments show that the injected electrons propagate some tens of microns before becoming trapped to form stable, negative molecular ions. Although these ions approximately follow Walden's rule the magnitude of the ion mobility i s lower than one would predict from the viscosity, and this is taken a s evidence that the ions are accompanied by a molecular cluster. There is evidence of an abrupt increase in ion mobility near the cholesteri c-to-isotropic liquid transition.