STUDIES ON SOME HOMOBIMETALLIC AND HETEROBIMETALLIC THIOCYANATO AND SELENOCYANATO BRIDGED COMPLEXES WITH 1,2-BIS(DIPHENYLPHOSPHINO)ETHANE

Authors
SINGH H SHUKLA SN SRIVASTAVA MK SRIVASTAVA RS
Citation
H. Singh et al., STUDIES ON SOME HOMOBIMETALLIC AND HETEROBIMETALLIC THIOCYANATO AND SELENOCYANATO BRIDGED COMPLEXES WITH 1,2-BIS(DIPHENYLPHOSPHINO)ETHANE, Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical, 32(9), 1993, pp. 799-801
Citations number
9
Categorie Soggetti
Chemistry
Journal title
Indian journal of chemistry. Sect. A: Inorganic, physical, theoretical & analytical → ACNP
ISSN journal
03764710
Volume
32
Issue
9
Year of publication
1993
Pages
799 - 801
Database
ISI
SICI code
0376-4710(1993)32:9<799:SOSHAH>2.0.ZU;2-U
Abstract
A few complexes of the type MM'(XCN)4 (dppe)2 (where M = Co2+, Ni2+, C d2+; M' = Cd2+, Hg2+; X = S, Se; dppe = 1,2-bis(diphenylphosphino)etha ne have been synthesized and characterized by elemental analyses, mola r conductance, magnetic moment, IR and electronic spectral studies. Th e softness parameters DELTATE(n)not-equal of the probable and alternat ive structures have also been calculated to derive the binding site of the thiocyanate/selenocyanate ligand.