KINETICS AND MECHANISM OF ETHANE-1, 2-DIO L BY ALKALINE HEXACYANOFERRATE(III) USING RUTHENIUM(III) CHLORIDE AS CATALYST

Authors
BALADO AM JIMENEZ FS
Citation
Am. Balado et Fs. Jimenez, KINETICS AND MECHANISM OF ETHANE-1, 2-DIO L BY ALKALINE HEXACYANOFERRATE(III) USING RUTHENIUM(III) CHLORIDE AS CATALYST, Anales de quimica, 89(3), 1993, pp. 313-318
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Anales de quimica → ACNP
ISSN journal
11302283
Volume
89
Issue
3
Year of publication
1993
Pages
313 - 318
Database
ISI
SICI code
1130-2283(1993)89:3<313:KAMOE2>2.0.ZU;2-R
Abstract
The kinetics of the oxidation reaction of ethane-1,2-diol by alkaline hexacyanoferrate (III) was studied spectrophotometrically. The effects of temperature and concentrations of hexacyanoferrate (III), diol, hi droxide ions and catalyst on reaction rate were analyzed. These result s sugget the formation of a complex between sustrate and ruthenium (II I) especies, which undergoes disproportionation in the rate determinin g step.