MELT RHEOLOGY, PHASE-STRUCTURE AND IMPACT PROPERTIES OF INJECTION-MOLDED SAMPLES OF ISOTACTIC POLYPROPYLENE ETHYLENE-PROPYLENE COPOLYMER (IPP EPR) BLENDS - INFLUENCE OF MOLECULAR-STRUCTURE OF EPR COPOLYMERS
L. Dorazio et al., MELT RHEOLOGY, PHASE-STRUCTURE AND IMPACT PROPERTIES OF INJECTION-MOLDED SAMPLES OF ISOTACTIC POLYPROPYLENE ETHYLENE-PROPYLENE COPOLYMER (IPP EPR) BLENDS - INFLUENCE OF MOLECULAR-STRUCTURE OF EPR COPOLYMERS, Polymer, 34(17), 1993, pp. 3671-3681
Isotactic polypropylene (iPP) based blends containing as second compon
ent ethylene-propylene copolymers (EPR) having, for constant propylene
(C3) content (wt/wt), different average molecular masses (M(w)BAR and
/or M(n)BAR) and, for constant average molecular mass, different molec
ular mass distributions (MMD) were investigated. The study was underta
ken to establish the influence of the melt phase viscosity ratio mu in
determining the average particle size of the EPR phase in the vicinit
y of the minimum expected according to the Taylor-Tomotika theory for
the average particle size versus log mu function, when mu is about equ
al to unity (in previous studies we have in fact reached mu values far
above 1). Moreoever, we also report the effects of molecular mass and
molecular mass distribution of the EPR phase on the melt rheological
behaviour of iPP/EPR blends, on the mode and state of dispersion of th
e EPR phase in the melt, as well as, in the solid state after iPP crys
tallization in injection moulded samples, on the crystalline lamellar
thickness and the thickness of the amorphous interlayer of iPP phase,
and finally on the impact properties of blend materials. It should be
pointed out that the apparent viscosity of all the iPP/EPR blends inve
stigated is expected to obey the logarithm additivity rule that applie
s at constant temperature and shear rate. The application of the Cross
-Bueche equation revealed that the zero-shear viscosity eta0 of these
iPP/EPR blends deviates positively from the logarithm additivity rule.
Assuming that the crystallization of the iPP phase freezes the morpho
logy of the EPR phase, a strict correlation is confirmed to exist betw
een the values of EPR particle size and EPR particle size range, as me
asured by scanning electron microscopy on samples in the solid state,
and mu value. The number average particle diameter (D(n)BAR) and the p
article size range of the EPR phase (D) are found to increase with inc
reasing mu value as expected according to the Taylor-Tomotika theory.
Finally, when the iPP phase crystallizes from its blends with EPR unde
r non-isothermal conditions, the phase structure developed in the blen
ds is characterized by lamellar thickness and interlamellar amorphous
layer thickness, respectively, lower and higher than that shown by pla
in iPP.