MICELLE FORMATION AND ANOMALOUS BEHAVIOR IN THE SYSTEM POLYSTYRENE-BLOCK-POLY(ETHYLENE PROPENE) POLY(ISOBUTENE) 5-METHYL-2-HEXANONE

Citation
Jr. Quintana et al., MICELLE FORMATION AND ANOMALOUS BEHAVIOR IN THE SYSTEM POLYSTYRENE-BLOCK-POLY(ETHYLENE PROPENE) POLY(ISOBUTENE) 5-METHYL-2-HEXANONE, Die Makromolekulare Chemie, 194(9), 1993, pp. 2497-2505
Citations number
18
Categorie Soggetti
Polymer Sciences
Journal title
ISSN journal
0025116X
Volume
194
Issue
9
Year of publication
1993
Pages
2497 - 2505
Database
ISI
SICI code
0025-116X(1993)194:9<2497:MFAABI>2.0.ZU;2-9
Abstract
Solubilization of poly(isobutene)a) by micelles of polystyrene-block-p oly(ethylene/propene) block copolymer with a copoly(ethylene/propene) core was investigated. The weight of poly(isobutene) solubilized was f ound to be proportional to the concentration of block copolymer in the solution. No influence of the presence of poly(isobutene) on the crit ical micelle temperatures has been found. However, the addition of pol y(isobutene) to the micellar solution seems to favour the anomalous be haviour found in micellar solutions of the block copolymers used in th is study.