In recent years significant advances have been made in materials chara
cterization and process development in optical fibers. This paper desc
ribes the important advances in defect characterization, processing an
d properties of hermetic fibers, and fabrication of fiber amplifiers.
The important defects in optical fibers are those associated with the
silica-glass network and the germanium dopant in affecting the short-w
avelength properties, and those associated with OH and H-2 contaminant
s in causing optical absorption near the communication wavelengths. Ch
aracterization of the photo-induced defects has provided fundamental u
nderstanding in diffraction grating formation and second harmonic gene
ration in fiber devices. Hermetic coatings have been deposited on opti
cal fibers, and hermetic fibers show remarkable improvements in both m
echanical and hydrogen reliabilities. Material properties of glass hos
ts and rare-earth dopants as well as the fiber designs and preform pro
cessing are shown to have significant impacts on the device performanc
e of fiber amplifiers.