Dissocative electron attachment processes have been observed in O- ele
ctron stimulated desorption from multilayer films of N2O molecules con
densed on polycrystalline platinum at 30 K. Kinetic energy distributio
ns, fixed kinetic energy O- yields and O- yields are reported. The ion
yields show dissociative attachment processes at 9 and 15 eV which ar
e not observed in the O- formation for isolated N2O molecules. The kin
etic energy distributions are broad and show that a value of about 0.5
eV is obtained for the most probable kinetic energy of O- ions whatev
er the incident electron energy. This indicates that the desorption dy
namics are driven by the dissociation dynamics of the N2O- resonant s
tates involved.